Journal Articles
2016
One-Pot Three-Component Synthesis of Vicinal Diamines via In Situ Aminal Formation and Carboamination
Ugo Orcel and Jerome Waser
Angew. Chem., Int. Ed. 2016, 55, 12881-12885. (DOI: 10.1002/anie.201607318) Green Access
Divergent Reactivity of Thioalkynes in Lewis Acid Catalyzed Annulations with Donor–Acceptor Cyclopropanes
Sophie Racine, Bence Hegedus, Rosario Scopelliti and Jerome Waser
Chem. Eur. J. 2016, 22, 11997-12001. (DOI: 10.1002/chem.201602755) Green Access
Gold-catalyzed direct alkynylation of tryptophan in peptides using TIPS-EBX
Gergely L. Tolnai, Jonathan P. Brand and Jerome Waser
Beilstein J. Org. Chem. 2016, 12, 745-749. (DOI: 110.3762/bjoc.12.74) Open Access!
Copper-Catalyzed Oxy-Alkynylation of Diazo Compounds with Hypervalent Iodine Reagents
Durga Prasad Hari and Jerome Waser
J. Am. Chem. Soc. 2016, 138, 2190-2193. (DOI: 10.1021/jacs.6b00278) Green Access
Nucleoside Analogues: Synthesis from Strained Rings
Sophie Racine, Jeremy Vuilleumier and Jerome Waser
Isr. J. Chem. 2016, 56, 566-577. (DOI: 10.1002/ijch.201500090) Green Access
Alkynylation of Thiols with Ethynylbenziodoxolone (EBX) Reagents: alpha- or beta- pi-Addition?
Matthew D. Wodrich, Paola Caramenti and Jerome Waser
Org. Lett. 2016, 18, 60-63. (DOI: 10.1021/acs.orglett.5b03241) Open Access!
2015
Enantioselective Synthesis of Homoallylic Azides and Nitriles via Palladium-Catalyzed Decarboxylative Allylation
Maria Victoria Vita, Paola Caramenti and Jerome Waser
Org. Lett. 2015, 17, 5832-5835. (DOI: 10.1021/acs.orglett.5b03002) Green Access
Room-Temperature Decarboxylative Alkynylation of Carboxylic Acids Using Photoredox Catalysis and EBX Reagents
Franck Le Vaillant, Thibaut Courant and Jerome Waser
Angew. Chem., Int. Ed. 2015, 54, 11200–11204. (DOI: 10.1002/anie.201505111) Green Access
Proteome-Wide Profiling of Targets of Cysteine-reactive Small Molecules by using Ethynyl Benziodoxolone Reagents
Daniel Abegg, Reto Frei, Luca Cerato, Durga Prasad Hari, Chao Wang, Jerome Waser and Alexander Adibekian
Angew. Chem., Int. Ed. 2015, 54, 10852–10857. (DOI: 10.1002/anie.201505641)
Collaboration: Biological results obtained in the Adibekian group at the University of Geneva.
Intramolecular Palladium-Catalyzed Alkene Carboalkynylation
Stefano Nicolai, Peter Swallow and Jerome Waser
Tetrahedron 2015, 71, 5959–5964. (DOI: 10.1016/j.tet.2015.06.030) Green Access
Platinum-Catalyzed Domino Reaction with Benziodoxole Reagents for Accessing Benzene-Alkynylated Indoles
Yifan Li and Jerome Waser
Angew. Chem., Int. Ed. 2015, 54, 5438-5442. (DOI: 10.1002/anie.201412321) Green Access
Palladium-Catalyzed Vicinal Amino Alcohols Synthesis from Allyl Amines by in Situ Tether Formation and Carboetherification
Ugo Orcel and Jerome Waser
Angew. Chem., Int. Ed. 2015, 54, 5250-5254. (DOI: 10.1002/anie.201500636) Green Access
[4+2]-Annulations of Aminocyclobutanes
Daniele Perrotta, Sophie Racine, Jeremy Vuilleumier, Florian de Nanteuil and Jerome Waser
Org. Lett. 2015, 17, 1030-1033. (DOI: 10.1021/acs.orglett.5b00149) Green Access
One-Pot, Three-Component Arylalkynyl Sulfone Synthesis
C. Chun Chen and Jerome Waser
Org. Lett. 2015, 17, 736-739. (DOI: 10.1021/acs.orglett.5b00015) Open Access!
General and Practical Formation of Thiocyanates from Thiols
Reto Frei, Thibaut Courant, Matthew D. Wodrich and Jerome Waser
Chem. Eur. J. 2015, 21, 2662-2668. (DOI: 10.1002/chem.201406171) Green Access
2014
Fast and Highly Chemoselective Alkynylation of Thiols with Hypervalent Iodine Reagents Enabled through a Low Energy Barrier Concerted Mechanism
Reto Frei, Matthew D. Wodrich, Durga Prasad Hari, Pierre-Antoine Borin, Clement Chauvier and Jerome Waser
J. Am. Chem. Soc. 2014, 136, 16563-16573. (DOI: 10.1021/ja5083014) Open Access!
Enantioselective Synthesis of Polycyclic Carbocycles via an Alkynylation–Allylation–Cyclization Strategy
Maria Victoria Vita, Pacal Mieville and Jerome Waser
Org. Lett. 2014, 16, 5768-5771. (DOI: 10.1021/ol5028333) Green Access
Room temperature alkynylation of H-phosphi(na)tes and secondary phosphine oxides with ethynylbenziodoxolone (EBX) reagents
C. Chun Chen and Jerome Waser
Chem. Commun. 2014, 50, 12923-12926. (DOI: 10.1039/C4CC06851C ) Green Access
Diester-Substituted Aminocyclopropanes: Synthesis and Use in [3+2]-Annulation Reactions
Eloisa Serrano, Florian de Nanteuil and Jerome Waser
Synlett 2014, 25, 2285-2288. (DOI: 10.1055/s-0034-1378512) Green Access
Synthesis of (Carbo)nucleoside Analogues by [3+2] Annulation of Aminocyclopropanes
Sophie Racine, Florian de Nanteuil, Eloisa Serrano and Jerome Waser
Angew. Chem., Int. Ed. 2014, 53, 8484-8487. (DOI: 10.1002/anie.201404832) Green Access
Dynamic Kinetic Asymmetric [3 + 2] Annulation Reactions of Aminocyclopropanes
Florian de Nanteuil, Eloisa Serrano, Daniele Perrotta and Jerome Waser
J. Am. Chem. Soc. 2014, 136, 6239-6242. (DOI: 10.1021/ja5024578) Green Access
2013
Total Synthesis and Biological Evaluation of Jerantinine E
Reto Frei, Davide Staedler, Aruna Raja, Raimo Franke, Florenz Sasse, Sandrine Gerber-Lemaire and Jerome Waser
Angew. Chem., Int. Ed. 2013, 52, 13373-13376. (DOI: 10.1002/anie.201305533) Green Access
Zinc–gold cooperative catalysis for the direct alkynylation of benzofurans
Yifan Li and Jerome Waser
Beilstein J. Org. Chem. 2013, 9, 1763-1767. (DOI: 10.3762/bjoc.9.204) Open Access!
Synthesis of Aminocyclobutanes by Iron-Catalyzed [2+2] Cycloaddition
Florian de Nanteuil and Jerome Waser
Angew. Chem., Int. Ed. 2013, 52, 9009–9013. (DOI: 10.1002/anie.201303803) Green Access
Catalytic Friedel–Crafts Reaction of Aminocyclopropanes
Florian de Nanteuil, Joachim Loup and Jerome Waser
Org. Lett. 2013, 15, 3738-3741. (DOI: 10.1021/ol401616a) Green Access
A Highly Chemoselective and Practical Alkynylation of Thiols
Reto Frei and Jerome Waser
J. Am. Chem. Soc. 2013, 135, 9620-9623. (DOI: 10.1021/ja4044196) Green Access
Azidation of Beta-Keto Esters and Silyl Enol Ethers with a Benziodoxole Reagent
Maria Victoria Vita and Jerome Waser
Org. Lett. 2013, 15, 3246-3249. (DOI: 10.1021/ol401229v) Green Access
Ethynylbenziodoxolones (EBX) as Reagents for the Ethynylation of Stabilized Enolates
Davinia Fernández González, Jonathan P. Brand, Régis Mondière and Jerome Waser
Adv. Synth. Catal. 2013, 355, 1631-1639. (DOI: 10.1002/adsc.201300266) Green Access
Gold-Catalyzed Regioselective Synthesis of 2- and 3-Alkynyl Furans
Yifan Li, Jonathan P. Brand and Jerome Waser
Angew. Chem., Int. Ed. 2013, 52, 6743-6747. (DOI: 10.1002/anie.201302210) Green Access
Pd(0)-Catalyzed Alkene Oxy- and Aminoalkynylation with Aliphatic Bromoacetylenes
Stefano Nicolai, Raha Sedigh-Zadeh , and Jerome Waser
J. Org. Chem. 2013, 78, 3783-3801. (DOI: 10.1021/jo400254q) Green Access
C2-Selective Direct Alkynylation of Indoles
Gergely L. Tolnai , Stephanie Ganss, Jonathan P. Brand and Jerome Waser
Org. Lett. 2013, 15, 112-115. (DOI: 10.1021/ol3031389) Green Access
Review Articles
2016
Benziodoxol(on)e Reagents as Tools in Organic Synthesis: The Background behind the Discovery at the Laboratory of Catalysis and Organic Synthesis
Jerome Waser
Synlett 2016, 27, 2761-2773. (DOI: 10.1055/s-0036-1589409) Green Access
Cyclic Hypervalent Iodine Reagents for Atom-Transfer Reactions: Beyond Trifluoromethylation
Yifan Li, Durga Prasad Hari, Maria Victoria Vita and Jerome Waser
Angew. Chem., Int. Ed. 2016, 55, 4436–4454. (DOI: 10.1002/anie.201509073) Green Access
2015
Alkynylation with Hypervalent Iodine Reagents
Jerome Waser
Top. Curr. Chem. 2015. (DOI: 10.1007/128_2015_660) Green Access
Cyclic Hypervalent Iodine Reagents and Iron Catalysts: The Winning Team for Late-Stage C-H Azidation
Maria Victoria Vita and Jerome Waser
Angew. Chem., Int. Ed. 2015, 54, 5290-5292. (DOI: 10.1002/anie.201501666) Green Access
2014
Taming Hypervalent Bonds and Strained Rings for Catalysis and Synthesis.
Florian de Nanteuil, Yifan Li, Maria Victoria Vita, Reto Frei, Eloisa Serrano, Sophie Racine and Jerome Waser
Chimia 2014, 68, 516-521. DOI: 10.2533/chimia.2014.516 . Green Access
Cyclization and annulation reactions of nitrogen-substituted cyclopropanes and cyclobutanes.
Florian de Nanteuil, Filippo De Simone, Reto Frei, Fides Benfatti, Eloisa Serrano and Jerome Waser
Chem. Commun. 2014, 50, 10912-10928. DOI: 10.1039/C4CC03194F . Green Access
2013
Gold-Catalyzed Alkynylation: Acetylene-Transfer instead of Functionalization.
Jonathan P. Brand, Yifan Li and Jerome Waser
Israel J. Chem. 2013, 53, 901-910. DOI:10.1002/ijch.201300044. Green Access
7. Synthesis of Saturated Heterocycles via Metal-Catalyzed Formal Cycloaddition Reactions that Generate a C–N or C–O Bond.
Jerome Waser
Topics in Heterocyclic Chemistry, Vol. 32 Synthesis of Heterocycles via Metal-Catalyzed Reactions that Generate one or More Carbon Heteroatom Bonds , Ed. J. P. Wolfe, Springer 2013, p. 225-270. Link Green Access
