S. Kampouri, T. N. Nguyen, M. Spodaryk, R. G. Palgrave, A. ZĂŒttel, B. Smit, and K. C. Stylianou, Concurrent Photocatalytic Hydrogen Generation and Dye Degradation Using MIL-125-NH2 under Visible Light Irradiation Adv Funct Mater,  28, 1806368 (2018) Doi: 10.1002/adfm.201806368
Abstract: The impact of different transition metalâbased coâcatalysts toward photocatalytic water reduction when they are physically mixed with visibleâlight active MILâ125âNH2 is first systematically studied. All coâcatalyst/MILâ125âNH2 photocatalytic systems are found to be highly stable after photocatalysis, with the NiO/MILâ125âNH2 and Ni2P/MILâ125âNH2 systems exhibiting high hydrogen (H2) evolution rates of 1084 and 1230 ”mol hâ1 gâ1, respectively. Second, how different electron donors affect the stability and H2 generation rate of the best Ni2P/MILâ125âNH2 system is investigated and it is found that triethylamine fulfils both requirements. Then, the electron donor is replaced with rhodamine B (RhB), a dye that is commonly used as a simulant organic pollutant, with the aim of integrating the photocatalytic H2 generation with the degradation of RhB in a single process. This is of supreme importance as replacing the costly (and toxic) electron donors with hazardous molecules present in wastewater makes it possible to oxidize organic pollutants and produce H2 simultaneously. This is the first study where a metalâorganic framework (MOF) system is used for this dualâphotocatalytic activity under visible light illumination and the proofâofâconcept approach envisions a sustainable wasteâwater remediation process driven by the abundant solar energy, while H2 is produced, captured, and further utilized.