List of chemical ancillaries for photolithography

Table of content

  1. Cleaning & Stripping
  2. Development
  3. Primers

The following document lists all the chemical ancillary products used for automatic and manual photolithography processes, in Zone 1, Zone 5, Zone 6, Zone 12 and Zone 13 of the cleanroom.

If you are looking for the list of photoresists or any chemicals for spincoating, you can find it here.

Important: The safety datasheet (SDS) and standard operating procedures (SOP) of all chemical products used in the cleanroom is available in the restricted area: https://cmiaccess.epfl.ch/restricted/indexWP.php

Cleaning & Stripping

Solvent

Location :

-1 : Plade Solvent (Z1)

+1 : Arias Lift-off (Z12), Arias Solvent (Z13)

Compatibility :

  • Water
  • All solvents in CMi

Safety:

H225

Location :

-1 : Plade Solvent (Z1)

+1 : Arias Lift-off (Z12), Arias Solvent (Z13)

Compatibility :

  • Water
  • IPA, XXX

Safety :

H225

H319, H336, EUH066

Location :

-1 : Plade Solvent (Z1)

+1 : Arias Solvent (Z13)

Compatibility :

  • Water
  • IPA

Safety :

H225

SVC-14 is based on dimethyl sulphoxide (DMSO). It performs similarly well as remover to NMP and is harmless in terms of occupational safety. Optimal for resist stripping, especially in liftoff process.

Location :

-1 : Plade Solvent (Z1)

+1 : Arias Lift-off (Z12)

Compatibility :

  • Water
  • IPA

Bath temperature : max 80°C

Datasheet : TDS SVC-14

Safety : No classification

NMP (1-methyl-2-pyrrolidone) is a very suitable solvent for removing photoresist coatings. The very low vapour pressure of NMP allows it to be heated to 80°C in order to remove even more cross-linked photoresist layers.

As NMP is classified as toxic and teratogenic, alternatives such as DMSO should be considered.

Location :

-1 : Plade Solvent (Z1)

+1 : Arias Lift-off (Z12)

Compatibility :

  • Water
  • IPA

Bath temperature : max 80°C

Datasheet : TDS Remover1165

Safety :

H360d H315, H319, H335
  • Based on oxalic acid dihydrate (<2.5%)
  • Safe & environment-friendly stripping solution
  • Work well with : negative, thick positive and chemically amplified photoresists
  • High metal compatibility
  • Not compatible with GaAs

Location :

-1 : –

+1 : Arias Solvent (Z13)

Compatibility :

  • Water

Bath temperature : max 80°C

Datasheet : TDS Technistrip Ni555

Safety : No classification

  • Based on 1-dodecene
  • Remover for the WaferBOND temporary bonding polymer.

Location :

-1 : –

+1 : Arias Solvent (Z13)

Compatibility :

  • Water

Bath temperature : max 80°C

H304 H226, H315

Base

  • TMAH-based (<2.5%)
  • Works well with highly crosslinked photoresists (e.g. through dry etching),
  • Works with other polymers: BCB, polyimide (uncured)
  • Not compatible with alkaline sensitve materials (Al, Cu, Ni, Ta/TaN, Ti/TiN)

Location :

-1 : –

+1 : Arias Base (Z13)

Compatibility :

  • Water

Bath temperature : not available at CMi

Datasheet : TDS Technistrip P1316

Safety :

 
H371, H373  H341, H318, H412

Development

Solvent

Development of negative Su8 and Nanoscribe’s IP* photoresists.

Location :

-1 : Plade Solvent (Z1)

+1 : Arias Solvent (Z13)

Compatibility :

  • Water
  • IPA

Safety :

H225

Development of negative photosensitive BCB, cyclotene 4022-XX series. DS3000 is based 1,3,5-triisopropylbenzene.

Location :

-1 :

+1 : Arias Solvent (Z13)

Compatibility :

  • IPA

Safety :

H304

Base

AZ 726 MIF is a metal ion-free, surfactant enhanced 0.26N TMAH (2.38%) developer solution optimized for puddle development processes.

It should be used at room temperature in puddle, spray, or immersion mode. It does not require additional dilution.

Location :

-1 : ACS200 (Z1), EVG150 (Z6)

+1 : Arias Base (Z13)

Datasheet : TDS AZ 726MIF

Safety :

H302 H371, H373 H290, H311, H314

AZ 400K is a potassium-based buffered developer solution that provides high throughput and contrast, particularly for thick photoresist film, such as AZ 10XT.

For optimal photoresist development, AZ 400 K is diluted with DI water with ratio between 1:3 (high speed) and 1:4 (high contrast).

Location :

-1 : ACS200 (Z1)

+1 : Arias Base (Z13)

Datasheet : TDS AZ 400K

Safety :

 H361d H290, H314

AZ 351B is a sodium-based buffered developer solution that provides high contrast and aspect ratio with almost any novolak-based positive photoresist. In CMI, it is used for the development of the AZ 1505 photoresist on Cr blanks.

For optimal photoresist development, AZ 351B is diluted with DI water with ratio between 1:3.5 (high speed) and 1:5 (high contrast).

Location :

-1 : Hamatech HMR900 (Z6)

+1 : Arias Base (Z13)

Datasheet : TDS AZ 351B

Safety :

 H360fd H290, H318

AZ Developer is an alkaline developer solution based on sodium metasilicate and phosphate that is optimised for minimal aluminium erosion. It also attacks many other alkaline-sensitive materials (copper, …) far less than other aqueous alkaline developers.

For optimal photoresist development, AZ Developer is diluted with DI water with ratio between 1:1 ratio.

Location :

-1 : EVG 150 (Z6)

+1 : Arias Base (Z13)

Datasheet : TDS AZ Developer

Safety :

H319

MF CD-26 is a metal ion-free, 0.26N TMAH (2.38%) developer solution, ideal for immersion development. Compared to AZ 726 MIF, it does not contain additional surfactants.

Location :

-1 : –

+1 : Arias Base (Z13)

Datasheet : TDS MF CD-26

Safety :

H302 H371, H373 H290, H311, H314

Primers

Hexamethyldisilazane (HMDS) is the an industry standard organosilane that promotes the adhesion of photoresists to Si, SiO2, Si3N4.

Due to its toxicity, it is applied in vapor form in a vacuum oven to prevent any safety risks.

Location :

-1 : ACS200 (Z1), YES 310TA (Z1), EVG150 (Z6), TEL Act 8 (Z5)

+1 : ATMsse VB20 (Sawatec SM200 – PR, Z13)

Safety :

H225 H302 H311, H314, H331

Adhesion promoter for polyimide films to Si, SiO2, TiO2, Si3N4. VM652 is a solution of an organosilane, (3-aminopropyl)tryethoxysilane (APTES), highly diluted in an organic solvent, 2-Methoxy-1-Propanol (PGME), that is suitable application by spincoating and drying.

Location :

-1 : Sawatec LSM-200 Polymide (Z6)

+1 : –

Safety :

H226 H336

Adhesion promoter for Cyclotene (BCB) and Su8 films to Si, SiO2, Si3N4. AP3000 is a solution of a proprietary organosilane, highly diluted in an organic solvent, 2-Methoxy-1-Propanol (PGME), that is suitable application by spincoating and drying.

Location :

-1 : –

+1 : Sawatec LSM-250 MISC (Z13)

Safety :

H226 H336

Adhesion promoter for ProTEK B3-25. ProTEK B3 primer is a solution of a proprietary organosilane, highly diluted in an organic solvent, 2-Methoxy-1-Propanol (PGME), that is suitable application by spincoating and drying.

Location :

-1 : –

+1 : Sawatec LSM-250 MISC (Z13)

Safety :

H225 H360 H336