MERBACH André E., Hon. Prof. – Publications ‒ ISIC ‐ EPFL

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Partitioning soil organic carbon into its centennially stable and active fractions with machine-learning models based on Rock-Eval (R) thermal analysis (PARTY(SOC)v2.0 and PARTY(SOC)v2.0 (EU))

L. Cecillon; F. Baudin; C. Chenu; B. T. Christensen; U. Franko et al.

Geoscientific Model Development. 2021-06-24. Vol. 14, num. 6, p. 3879-3898. DOI : 10.5194/gmd-14-3879-2021.

Partitioning soil organic carbon into its centennially stable and active fractions with machine-learning models based on Rock-Eval (R) thermal analysis (PARTY(SOC)v2.0 and PARTY(SOC)v2.0 (EU))

The Periodic Table and Kinetics?

Metal Complexes as MRI Contrast Enhancement Agents

Relaxivity of gadolinium(III) complexes: theory and mechanism

The Chemistry of Contrast Agents in Medical Magnetic Resonance Imaging

Lanthanide Complexes Formed with the Tri- and Tetraacetate Derivatives of Bis(aminomethyl)phosphinic Acid: Equilibrium, Kinetic and NMR Spectroscopic Studies

NMR Study of Ligand Exchange and Electron Self-Exchange between Oxo-Centered Trinuclear Clusters [Fe3(μ3-O)(μ-O2CR)6(4-R´py)3]+/0

Isomerization Mechanisms of Stereolabile tris- and bis-Bidentate Octahedral Cobalt(II) Complexes: X-ray Structure and Variable Temperature and Pressure NMR Kinetic Investigation

Multiple Frequency and Variable Temperature EPR study of Gd(III) polyaminocarboxylates: analysis and comparison of the magnetically dilute powder and the frozen solution spectra

Mechanism of Pyridine-Ligand Exchanges at the Different Labile Sites of 3d Heterometallic and Mixed Valence μ3-oxo Trinuclear Clusters

In vivo MRI assessment of a novel GdIII-based contrast agent designed for high magnetic field applications

Highly efficient MRI contrast agents

A benzene-core trinuclear GdIII complex: towards the optimization of relaxivity for MRI contrast agent applications at high magnetic field

Gadonanotubes as Ultrasensitive pH-Smart Probes for Magnetic Resonance Imaging

Physicochemical and MRI characterization of Gd3+-loaded polyamidoamine and hyperbranched dendrimers

Synthesis, structural characterization and applications of hyperbranched polymers based on L-lysine

A PCP-Pincer RuII-Terpyridine Building Block as a Potential “Antenna Unit” for Intramolecular Sensitization

Understanding Paramagnetic Relaxation Phenomena for Water-Soluble Gadofullerenes

Gadolinium(III) complexes of mono-and diethyl esters of monophosphinic acid analogue of DOTA as potential MRI contrast agents: solution structures and relaxometric studies

Design of Gd(III)-Based Magnetic Resonance Imaging Contrast Agents: Static and Transient Zero-Field Splitting Contributions to the Electronic Relaxation and Their Impact on Relaxivity

Mécanismes d’isomérisation et d’échange de ligand de complexes octaédriques labiles de cobalt (II)

Kinetic studies on the first dihydrogen aquacomplex, [Ru(H2)(H2O)5]2+: Formation under H2 pressure and catalytic H/D isotope exchange in water

Supramolecular Assembly of an Amphiphilic GdIII Chelate: Tuning the Reorientational Correlation Time and the Water Exchange Rate

Relevance of the Ligand Exchange Rate and Mechanism of fac-[(CO)3M(H2O)3]+ (M = Mn, Tc, Re) Complexes for New Radiopharmaceuticals

Unexpected Aggregation of Neutral, Xylene-Cored Dinuclear GdIII Chelates in Aqueous Solution

Phosphinic derivative of DTPA conjugated to a G5 PAMAM dendrimer: an 17O and 1H relaxation study of its Gd(III) complex

Water-Exchange Study Revealed Unexpected Substitution Behavior of [(CO)2(NO)Re(H2O)3]2+ in Aqueous Media

First in vivo MRI assessment of a self-assembled metallostar compound endowed with a remarkable high field relaxivity

Isomerization mechanisms of a labile Co(II) octahedral complex

A High-Frequency EPR Study of Frozen Solutions of Gd(III) Complexes: Straightforward Determination of the Zero-Field Splitting Parameters and Simulation of the NMRD Profiles

A Starburst-Shaped Heterometallic Compound Incorporating Six Densely Packed Gd3+ Ions

Positively Charged GdIII Cryptates: Slow, Associative Water Exchange

Multifrequency EPR studies of zero field splitting of Gd(III) based MRI contrast agents in solids and liquids

New polynuclear catalysts for atom-transfer radical addition reactions

Dinuclear, Bishydrated GdIII Polyaminocarboxylates with a Rigid Xylene Core Display Remarkable Proton Relaxivities

Inorganic and Bioinorganic Solvent Exchange Mechanisms

Rotational Dynamics Account for pH-Dependent Relaxivities of PAMAM Dendrimeric, Gd-Based Potential MRI Contrast Agents

Separation and Characterization of the Two Diastereomers for [Gd(DTPA-bz-NH2)(H2O)]2-, a Common Synthon in Macromolecular MRI Contrast Agents: Their Water Exchange and Isomerization Kinetics

Rigid M(II)L2Gd(III)2 (M=Fe, Ru) Complexes of a Terpyridine-Based Heteroditopic Chelate: A Class of Candidates for MRI Contrast Agents

Water and proton Exchange Processes on Metal Ions

Synthesis and complexation properties of DTPA-N,N”-bis[bis(n-butyl)]-N’-methyl-tris(amide). Kinetic stability and water exchange of its Gd3+ complex

The effect of pyridinecarboxylate chelating groups on the stability and electronic relaxation of gadolinium complexes

High Relaxivity Confined to a Small Molecular Space: A Metallostar-Based, Potential MRI Contrast Agent

Water-Soluble Gadofullerenes: Toward High-Relaxivity, pH-Responsive MRI Contrast Agents

Superparamagnetic gadonanotubes are high-performance MRI contrast agents

Reactivity of the novel organometallic aqua-ion [(CO)2(NO)Re(H2O) 3]2+: Kinetics of H2O substitution and 17O exchange of CO ligands

Destroying gadofullerene aggregates by salt addition in aqueous solution of Gd@C60(OH)x and Gd@C60[C(COOH2)]10

Fine-tuning water exchange on GdIII poly(amino carboxylates) by modulation of steric crowding

Lanthanide(III) chelates of DTPA bis(amide) glycoconjugates: potential imaging agents targeted at the asyaloglycoprotein receptor

New strategies for highly efficient medical MRI contrast agents

Reactivity of manganese, technetium and rhenium aquacarbonyl-complexes as potential precursors for radiopharmaceuticals

New insight into the chemistry of allymetals

Dinuclear gadolinium (III) chelates

[CpRu((R)-Binop-F)(H2O)][SbF6], a New Fluxional Chiral Lewis Acid Catalyst: Synthesis, Dynamic NMR, Asymmetric Catalysis, and Theoretical Studies

Metal complexes as MRI contrast enhancement agents

A novel 3D Nd(III)-Bi(III) coordination polymer generated from EDTA ligand

Novel heteroditopic chelate for self-assembled gadolinium(III) complex with high relativity

The Organometallic fac-[(CO)3Mn(H2O)3]+ Aqua ion: Base Hydrolysis and Kinetics of H2O Substitution

Richness of isomerism in labile octahedral Werner-type cobalt(II) complexes demonstrated by 19F NMR spectroscopy: Structure and stability

Destruction of perfluoroalkyl surfactant aggregates by β-cyclodextrin

Mechanistic Changeover for the Water Substitution on fac-[(CO)3Re(H2O)3]+ Revealed by High-Pressure NMR

Activation Volumes of Substitution Reactions on Neutral and Cationic Organometallic Platinum(IV) Complexes: Definite Proof of Selective Associative Activation

DMSO exchange on [Gd(DMSO)8]3+ – a variable pressure 17O NMR study

Calculated Volume and Energy Profiles for Water Exchange on t2g6 Rhodium(III) and Iridium(III) Hexaaquaions: Conclusive Evidence for an Ia Mechanism

Molecular dynamics simulations of the internal mobility of Gd3+-based MRI contrast agents: consequences for water proton relaxivity

Molecular dynamics of Gd(III) complexes in aqueous solution by HF EPR

Oxidation of Mixed-Valence CoIII/FeII Complexes Reversed at High pH: A Kinetico-Mechanistic Study of Water Oxidation

Lanthanide(III) complexes of DOTA-glycoconjugates: A potential new class of lectin-mediated medical imaging agents

Hydrogenation and hydroformylation in ionic liquids, water and biphasic systems

Complexes luminescents de lanthanides avec des dérivés du cyclène comme briques pour l’ingénierie de sondes analytiques biomédicales

Reactivity and fluxionality of late transition metal cluster compounds

Auto-organisation de complexes de lanthanide dans des structures supramoléculaires

Towards a rational design of Gd(III) complexes as contrast agents for magnetic resonance imaging

Structures and host-guest chemistry of self-assembled organometallic macrocycles

Preparation of (ethylene)-(propylene)-triaminepentaacetic acid derivatives for use in the production of pharmaceutical agents

MD simulations of acyclic and macrocyclic Gd3+-based MRI contrast agents: Influence of the internal mobility on water proton relaxivity

A Highly Stable Gadolinium Complex with a Fast, Associative Mechanism of Water Exchange

Reactivity of the Organometallic fac-[(CO)3ReI(H2O)3]+ Aquaion. Kinetic and Thermodynamic Properties of H2O Substitution

Towards binuclear polyaminocarboxylate MRI contrast agents? Spectroscopic and MD study of the peculiar aqueous behavior of the LnIII chelates of OHEC (Ln = Eu, Gd, and Tb): Implications for relaxivity

8S paramagnetic centers in molecular assemblies: Possible effect of their proximity on the water proton relaxivity